Thermodynamic system Totally Explained

In thermodynamics, a thermodynamic system, originally called a working substance, is defined as that part of the universe that's under consideration. A real or imaginary boundary separates the system from the rest of the universe, which is referred to as the environment or surroundings (sometimes called a reservoir.) A useful classification of thermodynamic systems is based on the nature of the boundary and the quantities flowing through it, such as matter, energy, work, heat, and entropy. A system can be anything, for example a piston, a solution in a test tube, a living organism, a planet, etc.

History of term

The first to develop the concept of a "thermodynamic system" was the French physicist Sadi Carnot who in his 1824 Reflections on the Motive Power of Fire studied what he called the working substance (system), for example typically a body of water vapor, in steam engines, in regards to the system's ability to do work when heat is applied to it. The working substance could be put in contact with either a heat reservoir (a boiler), a cold reservoir (a stream of cold water), or a piston (to which the working body could do work by pushing on it). In 1850, the German physicist Rudolf Clausius generalized this picture to include the concept of the surroundings and began to use the term "working body" when referring to the system. From his 1850 manuscript On the Motive Power of Fire Clausius states:

The article Carnot heat engine shows the original piston-and-cylinder diagram used by Carnot in discussing his ideal engine; below, we see the Carnot engine as is typically modeled in current use:
In the diagram shown, the “working body” (system), a term introduced by Clausius in 1850, can be any fluid or vapor body through which heat Q can be introduced or transmitted through to produce work. In 1824, Sadi Carnot, in his famous paper Reflections on the Motive Power of Fire, had postulated that the fluid body could be any substance capable of expansion, such as vapor of water, vapor of alcohol, vapor of mercury, a permanent gas, or air, etc. Although, in these early years, engines came in a number of configurations, typically Q_H was supplied by a boiler, wherein water was boiled over a furnace; Q_C was typically a stream of cold flowing water in the form of a condenser located on a separate part of the engine. The output work W here's the movement of the piston as it's used to turn a crank-arm, which was then typically used to turn a pulley so to lift water out of flooded salt mines. Carnot defined work as “weight lifted through a height”.

Overview

Thermodynamics is conducted under a system-centered view of the universe. All quantities, such as pressure or mechanical work, in an equation refer to the system unless labeled otherwise. Thermodynamics is basically concerned with the flow and balance of energy and matter in a thermodynamic system. Three types of thermodynamic systems are distinguished depending on the kinds of interaction and energy exchange taking place between the system and its surrounding environment:

Isolated systems are completely isolated in every way from their environment. They don't exchange heat, work or matter with their environment. An example of an isolated system would be an insulated rigid container, such as an insulated gas cylinder.

Closed systems are able to exchange energy (heat and work) but not matter with their environment. A greenhouse is an example of a closed system exchanging heat but not work with its environment. Whether a system exchanges heat, work or both is usually thought of as a property of its boundary.

Open systems: exchanging energy (heat and work) and matter with their environment. A boundary allowing matter exchange is called permeable. The ocean would be an example of an open system. In reality, a system can never be absolutely isolated from its environment, because there's always at least some slight coupling, even if only via minimal gravitational attraction. In analyzing a system in steady-state, the energy into the system is equal to the energy leaving the system (External Link

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As an example, consider the system of hot liquid water and solid table salt in a sealed, insulated test tube held in a vacuum (the surroundings). The test tube constantly loses heat (in the form of black-body radiation), but the heat loss progresses very slowly. If there's another process going on in the test tube, for example the dissolution of the salt crystals, it'll probably occur so quickly that any heat lost to the test tube during that time can be neglected. (Thermodynamics doesn't measure time, but it does sometimes accept limitations on the timeframe of a process.)

Systems in equilibrium

It is a fact that, for isolated systems, as time goes by, internal differences in the system tend to even out. Pressures and temperatures tend to equalize, as do density differences. A system in which all these equalizing processes have gone practically to completion, is considered to be in a state of thermodynamic equilibrium. Its thermodynamic properties are, by definition, unchanging in time. Systems in equilibrium are much simpler and easier to understand than systems which are not in equilibrium. Often, when analysing a thermodynamic process, it can be assumed that each intermediate state in the process is at equilibrium. This will also considerably simplify the situation. Thermodynamic processes which develop so slowly as to allow each intermediate step to be an equilibrium state are said to be reversible processes.

Open systems

In open systems, matter may flow in and out of the system boundaries. The first law of thermodynamics for open systems states: the increase in the internal energy of a system is equal to the amount of energy added to the system by matter flowing in and by heating, minus the amount lost by matter flowing out and in the form of work done by the system. The first law for open systems is given by:
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This expression is described by the diagram above.

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